lambda(2) = min_{v != 0, v'*v(1) = 0} v'*A*v / v'v
and the minimizing v is v(2).
Proof. Substitute the eigendecomposition A = Q*Lambda*Q', where Q is a orthogonal matrix whose columns v(i) are eigenvectors, and Lambda = diag(lambda(1), ..., lambda(n)) is a diagonal matrix of eigenvalues, into the expression in the theorem:
min_{v != 0, v'*v(1) = 0} v'*A*v / v'v
= min_{v != 0, v'*v(1) = 0} v'*Q*Lambda*Q'*v / v'*v
= min_{Qv != 0, v'*Q*Q'*v(1) = 0} v'*Q*Lambda*Q'*v / v'*Q*Q'*v
= min_{y != 0, y'*y(1) = 0} y'*Lambda*y / y'*y
where y = Q'*v and y(1) = Q'*v(1) = [1,0,...,0]'
= min_{y != 0, y_1 = 0} sum_i lambda(i)*y_i^2 / sum_i y_i^2
It is easy to see that this expression is minimized by taking
y = [0,1,0,...,0]', yielding lambda(2). Then v = Q*y = v(2), as desired. QED